the information of Ferrocene

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fanaco
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Joined: Wed Apr 21, 2010 11:46 am

the information of Ferrocene

Post by fanaco »

Ferrocene is an organometallic compound with the formula Fe(C5H5)2. It is the prototypical metallocene, a type of organometallic chemical compound consisting of two cyclopentadienyl rings bound on opposite sides of a central metal atom. Such organometallic compounds are also known as sandwich compounds. The rapid growth of organometallic chemistry is often attributed to the excitement arising from the discovery of ferrocene and its many analogues.

Ferrocene was first made unintentionally from the reaction of cyclopentadiene and iron powder in the 1950's, originally designed to couple the diene. Instead a lightly orange powder was obtained. The structure was confirmed by NMR. Led to an explosion of interest in d-block metal carbon bonds and brought about development and the now flourishing study of organometallic chemistry.

InFerrocene, the pi electrons of both the aromatic cyclopentadienyl rings are shared with the central iron ion, giving it an inert gas electron configuration. This makes ferrocene particularly stable. Ferrocene finds practical application as a catalyst in the making of ultra-high molecular weight polyethylene. This material is a new alternative to aramid, both can be used to make fibres for bulletproof clothing.
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